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Material Safety Data Sheet (MSDS) – Tetraethylammonium Acetate

1. Identification

Product Name: Tetraethylammonium Acetate
Chemical Family: Quaternary ammonium compound
Recommended Use: Laboratory chemical, research and synthesis
SDS Number: 107341
Supplier Details: Commercial lab reagent producers
Emergency Contact: Check local emergency numbers or poison control

2. Hazard Identification

GHS Classification: Eye irritant (Category 2A), Skin irritant (Category 2)
Label Elements: Signal word: Warning; Hazard pictograms: Exclamation mark
Hazard Statements: Causes serious eye irritation; Causes skin irritation
Precautionary Statements: Avoid contact with skin and eyes, Wear protective gloves and eye protection, Wash hands thoroughly after handling
Potential Health Effects: Eyes: redness, watering; Skin: redness, irritation; Inhalation: respiratory discomfort at high levels; Ingestion: gastrointestinal upset

3. Composition / Information on Ingredients

Chemical Name: Tetraethylammonium acetate
CAS Number: 1126-18-7
EC Number: 214-374-2
Formula: C10H23NO2
Weight Percent: 98-100%
Impurities: None significant for classification, trace manufacturing residues possible

4. First Aid Measures

Eye Contact: Rinse immediately with plenty of water for 15 minutes, holding eyelids open, seek medical attention if irritation persists
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, consult a physician for persistent irritation
Inhalation: Move to fresh air, monitor for breathing difficulty, provide artificial respiration if needed, seek medical care if symptoms develop
Ingestion: Rinse mouth, drink water if conscious, never give anything orally to an unconscious person, consult medical professionals without delay

5. Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, CO2, foam, water spray (avoid high-pressure jets)
Fire Hazards: Combustible at elevated temperatures, releases toxic fumes of nitrogen oxides and carbon oxides
Protective Equipment: Firefighters require self-contained breathing apparatus and full protective gear
Advice for Firefighters: Cool affected containers with water, evacuate area, remain upwind to avoid hazardous combustion products

6. Accidental Release Measures

Personal Precautions: Wear suitable protective equipment, ventilate area, avoid dust formation, prevent skin and eye contact
Environmental Precautions: Contain spill, prevent entry into drains, waterways, and soil
Clean-Up Methods: Sweep up dry material, avoid dust, place in sealed disposal container, clean area with plenty of water, ensure proper waste handling as per local regulation

7. Handling and Storage

Precautions for Safe Handling: Use in well-ventilated locations, avoid breathing dust, employ good laboratory hygiene practices, prohibit eating or smoking near substance
Storage Conditions: Store tightly closed in cool, dry, well-ventilated place, keep away from incompatible substances like oxidizers, acids; protect from moisture
Handling Measures: Use tools and containers resistant to corrosion and chemical reaction, ground containers when transferring to avoid static

8. Exposure Controls / Personal Protection

Exposure Limits: No established occupational exposure limits for this compound, observe good laboratory safety standards
Engineering Controls: Local exhaust ventilation or fume hood recommended during use
Personal Protection: Safety goggles, chemical-resistant gloves (nitrile or neoprene), lab coat, avoid direct contact with skin and eyes, use respiratory protection if dust or aerosols form
Hygiene Measures: Wash hands, face after handling, launder contaminated clothes before reuse

9. Physical and Chemical Properties

Appearance: White or off-white crystalline powder
Odor: Faintly amine-like
Molecular Weight: 189.3 g/mol
Melting Point: 180-185 °C (estimated)
Boiling Point: Decomposes before boiling
Solubility: Soluble in water, ethanol
pH: Near neutral in water
Vapor Pressure: Negligible at room temperature
Flash Point: Not available / Not flammable under standard conditions

10. Stability and Reactivity

Chemical Stability: Stable at ambient temperature and pressure, avoid excess moisture or heat
Hazardous Reactions: Can react with strong oxidizers and acids, may produce hazardous fumes if burned or decomposed
Decomposition Products: Carbon oxides, nitrogen oxides, toxic fumes on combustion
Conditions to Avoid: High heat, open flame, incompatible substances, prolonged exposure to air and light

11. Toxicological Information

Possible Routes of Exposure: Inhalation, ingestion, skin, eyes
Acute Toxicity: Oral LD50 (rat): Not thoroughly established, similar quaternary compounds generally have moderate toxicity
Local Effects: Eye and skin irritation, respiratory discomfort from dust
Chronic Effects: No long-term toxicity data, no evidence of carcinogenicity or reproductive hazards in available studies
Sensitization: No known sensitization in humans based on available data

12. Ecological Information

Aquatic Toxicity: Expected to have low to moderate acetate salt toxicity in aquatic environments, insufficient quantified data on endpoints
Persistence and Degradability: Likely biodegradable, quaternary ammonium group remains stable under some conditions
Bioaccumulation: Not expected to bioaccumulate significantly
Mobility in Soil: Highly soluble, may leach into waterways if released in large quantities
Other Adverse Effects: Avoid large releases to aquatic or terrestrial environments, follow local environmental guidelines

13. Disposal Considerations

Waste Handling: Dispose of product, contaminated packaging, or spill material via certified chemical waste contractor
Methods of Disposal: Incinerate in permitted facility or chemically treat as required by authority, avoid landfill disposal if possible
Container Disposal: Rinse empty containers with water, treat rinse as hazardous waste, do not reuse containers

14. Transport Information

UN Number: Not regulated for transport under most international guidelines
Transport Hazard Class: Non-hazardous chemical (check updates if regulations change)
Packing Group: Not assigned
Precaution for Transport: Protect from excessive heat, moisture, store away from food and feedstuffs, label clearly
Special Precautions: Avoid damaging packaging during transport, keep upright, ensure secondary containment

15. Regulatory Information

Inventory Status: Listed on EU REACH, US TSCA, and similar major chemical registries
Labeling Requirements: Conforms to OSHA HazCom, GHS guidelines, includes hazard pictograms, signal word, statements
Restrictions: Not restricted for commercial and laboratory use under present regulations
Other Requirements: Storage, transport, waste procedures to follow chemical safety, environmental and occupational guidelines as set by jurisdictional authorities