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Material Safety Data Sheet: Hydrogenated Tallow Amine Polyoxyethylene Ether

Identification

Product Name: Hydrogenated Tallow Amine Polyoxyethylene Ether
Chemical Family: Nonionic surfactant
Synonyms: Fatty amine ethoxylate, Ethoxylated tallow amine
CAS Number: Varies by ethoxylation degree, typically 61791-26-2
Recommended Use: Emulsifier, wetting agent, textile and cleaning industries, adjuvant for agrochemicals
Supplier: [Supplier information required]
Emergency Phone Number: [Emergency contact required]

Hazard Identification

Classification: Eye irritation Category 2A, Skin irritation Category 2, Acute toxicity (oral) Category 4, Hazardous to the aquatic environment – Chronic Category 2
Label Elements: Signal word: WARNING. Pictograms: Exclamation mark and Environment.
Hazard Statements: Causes serious eye irritation. Causes skin irritation. Harmful if swallowed. Toxic to aquatic organisms with long lasting effects.
Precautionary Statements: Avoid breathing mist or vapors. Wear protective gloves, clothing, and eye protection. Wash skin thoroughly after handling. Avoid release to environment.

Composition / Information on Ingredients

Chemical Name: Hydrogenated tallow amine polyoxyethylene ether
Active Ingredient: 90-100% (content varies with product grade)
Other Components: Trace impurities may include unreacted tallow amine and polyoxyethylene glycol
CAS Numbers: 61791-26-2 (Hydrogenated tallow amine ethoxylate), 61788-85-0 (Hydrogenated tallow amine)
Formulation: Liquid or waxy solid depending on EO content

First Aid Measures

Inhalation: Remove victim to fresh air, keep warm and at rest. Seek medical attention if symptoms persist.
Skin Contact: Wash with soap and plenty of water. Remove contaminated clothing. If skin irritation or rash appears, consult medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses if present and continue rinsing. Seek medical help.
Ingestion: Rinse mouth with water. Do not induce vomiting unless instructed by medical personnel. Call a poison center or doctor.
Most Important Symptoms: Eye and skin irritation, possible stomach pain, headache, or nausea if swallowed.

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Special Hazards: Product may emit toxic fumes under fire conditions, such as carbon oxides and nitrogen oxides.
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing.
Specific Methods: Cool containers with water spray to prevent pressure build-up. Avoid runoff into waterways.

Accidental Release Measures

Personal Precautions: Evacuate area, keep unnecessary people away. Use personal protective equipment to prevent contact with skin or eyes.
Environmental Precautions: Prevent spillage from entering drains, watercourses, or soil.
Containment and Clean-Up: Absorb spill with earth, sand, or other non-combustible material. Collect in suitable container for disposal. Wash spill area with plenty of water. Maintain ventilation during cleanup operations.

Handling and Storage

Handling: Use only in well-ventilated areas. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke while working with the product.
Storage: Store tightly closed in original containers in a dry, cool, well-ventilated place. Keep away from incompatible materials, strong acids, and oxidizing agents. Protect from heat, sparks, open flames, and direct sunlight. Ensure containers are clearly labeled.

Exposure Controls and Personal Protection

Engineering Controls: Provide local exhaust ventilation. Install eyewash stations and emergency showers where chemical is handled frequently.
Personal Protection: Wear chemical-resistant gloves (e.g. nitrile), safety goggles, and chemical-resistant clothing. In poorly ventilated areas, use suitable respiratory equipment.
Occupational Exposure Limits: Not established for this specific compound. Observe limits for nuisance dusts or mists.
Hygiene Measures: Wash thoroughly after handling. Remove and wash contaminated clothing before reuse.

Physical and Chemical Properties

Appearance: Pale yellow to amber viscous liquid or solid wax
Odor: Weak, fatty amine odor
pH: 9.0–11.0 (1% solution in water)
Melting Point: 20°C–45°C (depends on EO chain length)
Boiling Point: >200°C (decomposes before boiling)
Solubility: Soluble in water and ethanol
Vapor Pressure: Low at 20°C
Density: 0.95–1.05 g/cm³ at 25°C
Viscosity: Highly viscous at room temperature
Flash Point: >150°C
Partition Coefficient (log Kow): Estimated 2–4
Auto-Ignition Temperature: Not available

Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures
Reactivity: May react with strong acids, strong oxidizing agents, and reducing agents
Decomposition Products: Under combustion: carbon monoxide, carbon dioxide, nitrogen oxides, and possibly formaldehyde
Conditions to Avoid: Excess heat, open flames, direct sunlight, storage with incompatible materials
Polymerization: No dangerous polymerization expected.

Toxicological Information

Acute Toxicity: Oral LD50 (rat): estimated 1,000–2,000 mg/kg
Skin Irritation: Causes skin irritation and possible sensitization with prolonged contact.
Eye Irritation: Causes serious eye irritation; potential for corneal injury.
Inhalation: May cause respiratory tract irritation if mists are inhaled.
Long-Term Exposure: No evidence of carcinogenicity, mutagenicity, or reproductive toxicity to date. Repeated skin contact may cause dermatitis.
Sensitization: May cause allergic skin reactions in sensitive individuals.

Ecological Information

Toxicity: Harmful to aquatic life with long lasting effects (LC50 for aquatic organisms: 1–10 mg/L)
Persistence and Degradability: Not readily biodegradable; persistence expected in the environment.
Bioaccumulative Potential: Moderate potential based on estimated log Kow.
Mobility in Soil: May leach slowly through soil, depending on conditions.
Other Effects: High concentrations may disrupt wastewater treatment or aquatic systems.

Disposal Considerations

Waste Treatment Methods: Dispose of according to local, national, and regional regulations for hazardous waste
Product Disposal: Incinerate in approved facility with afterburner and scrubber; avoid landfilling substantial amounts.
Container Disposal: Empty containers should be rinsed and offered for recycling or reconditioning if possible.
Contaminated Packaging: Treat packaging as hazardous if not properly cleaned.

Transport Information

UN Number: Not regulated under many transport regulations, but check locally
Proper Shipping Name: Environmentally hazardous substance, liquid, n.o.s. (Hydrogenated tallow amine polyoxyethylene ether)
Hazard Class: 9 (Environmentally hazardous)
Packing Group: III
IMDG / ICAO / IATA: Consider marine pollutant labeling if shipped over water
Special Precautions: Prevent leaks/spills during loading/unloading; protect containers against physical damage.

Regulatory Information

TSCA Status: Listed
REACH Registration: Registered under EC No. 500-234-8 (tailored to composition); may require authorization for use in EU
OSHA Status: Not considered hazardous under OSHA regulations, but classified as hazardous under GHS
Labeling Requirements: GHS compliant labeling needed in most jurisdictions
SARA 313: Not subject to SARA Title III Section 313 reporting
Other Registrations: Consult local, state, and international regulations for specific requirements regarding handling, storage, and reporting.