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Material Safety Data Sheet: Dioctyl Methyl Tertiary Amine

Identification

Chemical Name: Dioctyl Methyl Tertiary Amine
Synonyms: N,N-Dioctyl-N-methylamine
Formula: C21H45N
CAS Number: 6137-30-2
Molecular Weight: 311.60 g/mol
Manufacturer: [Company Information]
Emergency Contact: [Phone Number]
Recommended Use: Surfactant, extractant, flotation agent.

Hazard Identification

Hazard Classification: Flammable liquid, skin irritation, eye damage, aquatic hazard
Signal Word: Danger
Hazard Statements: Causes serious skin irritation and eye damage; may cause respiratory irritation; harmful to aquatic organisms with long lasting effects; flammable liquid and vapor
GHS Pictograms: Flame, exclamation mark, corrosion, environment
Route of Exposure: Inhalation, ingestion, skin and eye contact
Symptoms: Burning sensation, coughing, redness, watering eyes, abdominal pain, dizziness.

Composition / Information on Ingredients

Main Ingredient: Dioctyl Methyl Tertiary Amine
Concentration: 98-100%
Impurities: Dioctylamine, methylamine (<0.5%)
Additives: None
EINECS Number: 228-051-9

First Aid Measures

Inhalation: Move the person to fresh air. Seek medical attention for persistent symptoms such as coughing, wheezing, shortness of breath, or dizziness. Oxygen or artificial respiration may be needed.
Skin Contact: Remove contaminated clothing and shoes quickly. Wash with copious amounts of water and mild soap. If irritation or redness persists, see a doctor.
Eye Contact: Rinse opened eyes thoroughly with running water for at least 15 minutes, holding eyelids apart. Do not rub the eyes. Remove contact lenses if present and easy to do. Get medical attention immediately.
Ingestion: Rinse mouth well with water. Do not induce vomiting. Give small amounts of water to dilute. Never give anything by mouth to an unconscious person. Seek immediate medical care.

Fire-Fighting Measures

Suitable Extinguishing Media: Use CO2, alcohol-resistant foam, dry chemical, or water spray.
Special Hazards: Vapors may form flammable mixtures with air. Can release hazardous fumes such as nitrogen oxides, carbon monoxide, and amines under fire conditions. Containers can burst if exposed to extreme heat.
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective gear.
Fire-Fighting Instructions: Evacuate area. Fight fire from upwind. Cool nearby containers with water spray. Do not allow runoff from fire control to enter drains or watercourses.

Accidental Release Measures

Personal Precautions: Ventilate area. Avoid breathing vapors or mist. Remove all sources of ignition. Wear chemical splash goggles, gloves, and suitable protective clothing.
Methods for Cleanup: Stop leak if safe to do so. Dike spilled material with inert absorbent (sand, earth, vermiculite). Collect into containers for disposal. Wash area with water after clean-up. Prevent entry into sewers, basements, or confined spaces.
Environmental Precautions: Prevent release into the environment. Notify authorities if large spills reach watercourses or sewers.

Handling and Storage

Handling: Use only in well-ventilated areas. Keep away from heat, sparks, open flames, and hot surfaces. Use spark-proof tools. Avoid all contact with skin, eyes, and clothing. Wear protective gear. No smoking near chemicals.
Storage: Store in tightly sealed original container. Keep in a cool, dry, well-ventilated place away from incompatible materials such as acids and oxidizing agents. Protect from sunlight. Store away from food and drink.
Specific Requirements: Follow regulations for flammable liquids. Keep storage containers grounded and bonded.

Exposure Controls and Personal Protection

Engineering Controls: Provide local exhaust ventilation, especially where vapors or aerosols may be generated.
Eye Protection: Chemical goggles or face shield.
Skin Protection: Impervious gloves. Long-sleeved clothing. Chemical resistant boots.
Respiratory Protection: Use approved respirators if exposure limits are exceeded or in case of inadequate ventilation.
Workplace Monitoring: Regular air monitoring for amine vapors. Ensure emergency eyewash and safety shower stations are accessible.
Environmental Controls: Prevent leakages to the environment. Use containment to avoid soil and water contamination.

Physical and Chemical Properties

Appearance: Clear to slightly yellow oily liquid
Odor: Amine-like, fishy odor
Odor Threshold: Not established
pH: Weak alkaline
Melting Point: -18°C
Boiling Point: 160-170°C at 2 kPa (decomposes)
Flash Point: 90°C (closed cup)
Evaporation Rate: Not available
Flammability: Flammable
Vapor Pressure: 0.3 Pa at 20°C
Vapor Density: >1 (Air = 1)
Relative Density: 0.84–0.86 g/cm3 at 25°C
Solubility: Slightly soluble in water; soluble in alcohol, ether, and organic solvents
Partition Coefficient (Log Kow): >7
Auto-ignition Temperature: 250°C
Decomposition Temperature: 180°C
Viscosity: 36 mPa·s at 20°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions.
Conditions to Avoid: High heat, direct sunlight, open flames, sparks.
Incompatible Materials: Oxidizers, strong acids, acid chlorides.
Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, ammonia, other toxic fumes.
Reactivity: Can react exothermically with acids or oxidizers.

Toxicological Information

Acute Toxicity: LD50 (oral, rat) > 2,000 mg/kg; LD50 (dermal, rabbit) > 2,000 mg/kg.
Skin Corrosion/Irritation: Causes serious skin burns.
Serious Eye Damage: Causes severe eye irritation and damage.
Respiratory Sensitization: May cause respiratory irritation.
Ingestion Effects: Nausea, abdominal pain, vomiting, diarrhea.
Chronic Toxicity: Long-term exposure can lead to dermatitis or respiratory tract irritation.
Carcinogenicity: No data indicating carcinogenic potential.
Mutagenicity: No data indicating genetic toxicity.
Reproductive Toxicity: No data indicating reproductive harm.

Ecological Information

Ecotoxicity: Harmful to aquatic life with long-lasting effects. LC50 (fish): 1–10 mg/L.
Persistence and Degradability: Not readily biodegradable. May persist in soil and water environments.
Bioaccumulative Potential: Log Kow > 7 indicates high potential to accumulate in aquatic organisms.
Mobility in Soil: Low mobility due to high hydrophobicity and affinity for organic matter.
Other Adverse Effects: Toxic to algae and invertebrates in aquatic environments.

Disposal Considerations

Disposal Methods: Dispose of contents and container in accordance with national and local regulations. Combust in a chemical incinerator equipped with afterburner and scrubber if possible.
Waste Code: Assign according to applicable regional regulations.
Contaminated Packaging: Empty containers should be triple-rinsed, then offered for recycling or reconditioning. Disposal should comply with local environmental control.
Precautions: Avoid discharge to sewers or natural waters. Consult with chemical waste disposal specialists.

Transport Information

UN Number: UN 2734
Proper Shipping Name: Amines, liquid, corrosive, flammable, n.o.s. (Dioctyl Methyl Tertiary Amine)
Transport Hazard Class: 3 (flammable liquids) / 8 (corrosive substances)
Packing Group: II
Label: Flammable liquid, corrosive
Marine Pollutant: Yes
Special Precautions: Keep away from heat, spark, open flame. Avoid rough handling. Use proper packaging.

Regulatory Information

OSHA Status: Classified as hazardous.
TSCA Inventory: Listed.
REACH Status: Registered.
SARA Title III: Section 311/312: Immediate, Fire, Delayed hazards
WHMIS Classification: D2B (Toxic), B2 (Flammable), E (Corrosive)
Other International Regulations: Subject to regulations in the EU, Canada, Australia, and other jurisdictions regarding hazardous substances.
Labeling: Must show correct hazard symbols, precautionary statements, and emergency contact.