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Material Safety Data Sheet (MSDS) – Antibacterial Hand Sanitizer

Identification

Product Name: Antibacterial Hand Sanitizer
Recommended Use: Hand antiseptic for reducing bacteria
Manufacturer: GlowCare Labs, 124 Maple Avenue, Los Angeles, CA 90018
Phone Number: 1-800-555-2273 (Mon-Fri 8am-6pm PST)
Emergency Contact: Chemtel 1-800-255-3924 (24/7 response line)
Product Type: Topical antibacterial gel
Product Code: GCL-HS-2048
Date of Issue: March 12, 2024
Revision Number: 4.1

Hazard Identification

Classification: Flammable liquid, eye irritant, mild respiratory irritant
Hazard Pictogram: Flame, exclamation mark
Signal Word: Danger
Hazard Statements: Contains alcohol, flammable, may cause eye irritation, can cause drowsiness or dizziness from inhalation
Precautionary Statements: Keep away from heat and open flame, use in a well-ventilated area, avoid contact with eyes, keep out of reach of children
Potential Health Effects: Eye redness, stinging, mild respiratory discomfort, headache with prolonged inhalation

Composition / Information on Ingredients

Ethyl Alcohol (Ethanol): 70% by weight (CAS #: 64-17-5), active ingredient
Water: 25% by weight (CAS #: 7732-18-5), solvent
Glycerin: 2% by weight (CAS #: 56-81-5), moisturizer
Isopropyl Myristate: 1% by weight (CAS #: 110-27-0), emollient
Carbomer: 0.8% by weight (CAS #: 9003-01-4), thickener
Triethanolamine: 0.5% by weight (CAS #: 102-71-6), neutralizing agent
Fragrance: 0.4% by weight (proprietary blend), scent
Aloe Barbadensis Leaf Juice: 0.3% by weight, botanical skin conditioner

First Aid Measures

Inhalation: Move to fresh air, provide oxygen if needed, seek medical advice for breathing difficulty
Skin Contact: Wash hands thoroughly with water, discontinue use if skin redness or irritation develops
Eye Contact: Rinse gently for at least 15 minutes, remove contact lenses after first 5 minutes, consult an ophthalmologist if burning or redness persists
Ingestion: Do not induce vomiting, drink water to dilute, contact poison center immediately, seek medical attention if symptoms occur
Most Important Symptoms: Eye irritation, drowsiness, mild skin dryness in frequent use
Notes for Doctor: Treat symptomatically, monitor respiratory and eye health, provide supportive care as needed

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, CO2, alcohol-resistant foam
Unsuitable Media: Water spray may spread fire
Hazardous Combustion Products: Carbon monoxide, carbon dioxide, unidentified organic compounds
Protective Equipment for Firefighters: Self-contained breathing apparatus, full protective gear
Fire/Explosion Hazards: Vapors may form flammable mixtures in air, flashback possible along vapor trail
Special Information: Move containers from fire area if possible without risk, cool containing vessels with water spray

Accidental Release Measures

Personal Precautions: Remove ignition sources, supply adequate ventilation, avoid contact with eyes and prolonged skin contact
Protective Equipment: Nitrile gloves, chemical goggles, long sleeves
Containment: Absorb spill with sand, earth, vermiculite, or inert absorbent
Cleanup Method: Collect in containers for disposal, clean surface with water, ventilate area
Environmental Precautions: Prevent liquid from entering drains, water sources, or soil
Spill Reporting: Notify proper authorities if large quantities contaminate storm drains, sewers, or local waterways

Handling and Storage

Handling: Store in original, tightly closed containers; avoid rough handling to prevent leaks; maintain distance from heat and ignition sources; use only non-sparking tools; keep away from incompatible materials such as oxidizers
Storage: Keep in cool, dry, ventilated area; do not store above 30°C; keep away from sunlight; segregate from food and beverages
Incompatibilities: Strong oxidizing agents, acids, alkalis
Special Storage Considerations: Post “No Smoking” signage, use grounded transfer equipment, maintain good housekeeping practices to reduce fire hazard

Exposure Controls and Personal Protection

Engineering Controls: Provide general mechanical ventilation, use explosion-proof ventilators, keep dispensers securely capped
Personal Protective Equipment: Nitrile or vinyl gloves for bulk handling; safety goggles in case of splash risk; lab coat or apron for large volumes
Respiratory Protection: Not needed for routine small-scale use; use organic vapor mask in high concentrations or spill response
Occupational Exposure Limits: Ethanol ACGIH TLV: 1000 ppm (1880 mg/m³); monitor air in splash-prone settings
Hygiene Measures: Wash exposed skin with soap and water after handling; do not eat, drink, or smoke during use
Environmental Protection: Prevent excessive product discharge into environment; maintain compliance with workplace air quality standards

Physical and Chemical Properties

Appearance: Clear, colorless gel
Odor: Alcohol-like, with mild synthetic fragrance
pH: 6.2 - 7.5
Boiling Point: 78°C (ethanol component)
Melting Point: Not applicable (gel form)
Flash Point: 21°C (closed cup; highly flammable)
Vapor Pressure: 44 mmHg @ 20°C (ethanol)
Vapor Density: 1.6 (air = 1)
Solubility: Miscible with water
Evaporation Rate: Faster than water
Relative Density: About 0.89 - 0.91 g/cm³
Viscosity: Medium, does not run easily on skin
Partition Coefficient: Not determined
Auto-ignition Temperature: ~362°C
Decomposition Temperature: Not established

Stability and Reactivity

Chemical Stability: Stable under normal handling and storage conditions
Conditions to Avoid: Spark, open flames, excess heat, strong sunlight
Possibility of Hazardous Reactions: Risk of vapor buildup and combustion in unventilated spaces
Incompatible Materials: Strong oxidizers (chlorine, peroxides), acids, alkalis
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, acrid smoke
Polymerization: Will not occur during intended use

Toxicological Information

Acute Toxicity: Small oral doses may cause dizziness, stomach ache; repeated ingestion toxic
Skin Contact: Non-toxic in intended use but may dry out skin with repeated exposure
Eye Contact: Causes moderate discomfort, redness, watering
Inhalation: Can irritate nose and throat, trigger mild headache or drowsiness with high vapor
Chronic Effects: Frequent long-term skin exposure may lead to dry, cracked hands
Carcinogenicity: Not classified as carcinogenic by IARC, NTP, OSHA
Mutagenicity: No evidence of mutagenic effects under normal use
Reproductive Toxicity: No known effects in small, topical exposures
Signs of Overexposure: Dizziness, nausea, burning eyes, shortened attention, fatigue

Ecological Information

Ecotoxicity: Large volumes present risk to aquatic life, short-term fish and daphnid toxicity (LC50 – 11,200 mg/L for 48h, rainbow trout, ethanol)
Persistence/Degradability: Readily biodegradable in water and air, ethanol degrades rapidly
Bioaccumulative Potential: Does not bioaccumulate per product ingredients
Mobility in Soil: Product seeps quickly in moist environments, low soil retention
Other Adverse Effects: Avoid discharges to waterways, reduction of dissolved oxygen possible in bulk spills

Disposal Considerations

Waste Disposal Method: Treat as hazardous flammable waste; collect in sealed containers, dispose per local, state, and federal regulations
Small Amounts: Rinse container with water before disposal, use in accordance with label
Contaminated Packaging: Dispose of using licensed waste handler, do not reuse packaging for other substances
Special Instructions: Contact licensed waste disposal services for large volumes; comply with landfill requirements and burn bans imposed by local law; do not pour into drains or sewers

Transport Information

UN Number: UN1170
UN Proper Shipping Name: Ethanol solutions
Transport Hazard Class: 3 (flammable liquids)
Packing Group: II
Labels Required: Flammable liquid
Special Precautions: Secure containers upright, limit to permitted volumes per vehicle, ventilate transport vehicles; keep shipping documents available
International Transport Regulations: DOT, ADR, IATA, IMDG applicable

Regulatory Information

TSCA Listing: All ingredients listed or exempt
OSHA Hazard Communication: Meets hazard criteria for flammable liquid, eye and skin irritant
SARA Title III: No Threshold Planning Quantity ingredients; Section 313 not triggered
California Proposition 65: No listed substances in this product
FDA: OTC antiseptic use permitted
WHMIS Classification (Canada): D2B, B2
Other Notices: Compliant with EU Cosmetic Regulation (EC) No 1223/2009 for topical use, upholds GHS labeling standards, reference available for full ingredient transparency