Suyuan Chemical
지식

Material Safety Data Sheet (MSDS) for 15-Crown-5

Identification

Product Name: 15-Crown-5
Synonyms: 1,4,7,10,13-Pentaoxacyclopentadecane
CAS Number: 33100-27-5
Recommended Uses: Phase transfer catalyst, organic synthesis, chelating agent
Supplier Contacts: Reach out to chemical distributors or manufacturing partners for sourcing support and technical services.
Emergency Phone: Local poison control or specialty chemical hotline

Hazard Identification

Classification: Eye irritation, Skin irritation, Target organ toxicity suspected
Potential Hazards: May cause irritation to eyes, skin, and respiratory system, possible drowsiness, or dizziness under prolonged exposure
Signal Word: Warning
Pictograms: Exclamation mark
GHS Hazards: H315 (skin), H319 (eye), H335 (respiratory tract)
Precautionary Statements: Avoid breathing dust, fumes, and direct contact; wash exposed skin thoroughly; use protective equipment as needed

Composition / Information on Ingredients

Chemical Name: 15-Crown-5
Molecular Formula: C10H20O5
Molecular Weight: 220.27 g/mol
Concentration: ≥98%, technical grade or higher
Impurities: Trace amounts of ethers, possible water content

First Aid Measures

Inhalation: Move to fresh air, seek medical attention if symptoms develop such as coughing, sore throat, or dizziness; artificial respiration or oxygen if required
Skin Contact: Remove contaminated clothing, flush skin with copious water for several minutes, seek medical advice for persistent irritation
Eye Contact: Use eye wash station for at least 15 minutes, keep eyelids open, consult a physician if discomfort persists
Ingestion: Rinse mouth, do not induce vomiting, get medical help immediately; information on possible delayed symptoms should be relayed to responders

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical powder, carbon dioxide, foam, water spray for larger fires
Specific Hazards: Combustion releases carbon oxides, hazardous vapors possible if material decomposes
Protective Equipment: Firefighters use full protective gear with self-contained breathing apparatus; skin and eye protection recommended
Special Procedures: Approach from upwind, contain run-off water, prevent entry into water sources and drains

Accidental Release Measures

Personal Precautions: Ensure adequate ventilation, avoid breathing dust/vapors, put on chemical-resistant gloves and eye protection
Environmental Precautions: Prevent spillage from entering soil, waterways, and sewer systems; inform authorities if significant release occurs
Cleanup Methods: Collect and transfer spilled material to secure, labeled containers for disposal; wash down area with water and detergent; dispose of contaminated material following regulations

Handling and Storage

Handling: Use in well-ventilated environments, avoid contact with skin, eyes, and clothing, handle with compatible chemical-resistant gloves and eye protection
Hygiene Measures: Wash thoroughly after handling, do not eat, drink, or smoke near material
Storage Conditions: Store in tightly closed containers, keep in a cool, dry, well-ventilated area away from incompatible substances or open flames; limit exposure to moisture and heat

Exposure Controls and Personal Protection

Engineering Controls: Fume hood or local exhaust ventilation, splash-proof sinks for eye and skin washing
Personal Protection: Gloves (nitrile or neoprene), safety goggles, lab coat or apron, in certain settings a respirator rated for organic vapors
Exposure Limits: No established occupational exposure limits, maintain levels as low as reasonably achievable
Environmental Controls: Use closed systems where possible, monitor air quality for vapors, provide spill kits

Physical and Chemical Properties

Appearance: Colorless to pale yellow liquid
Odor: Characteristic ether-like
Melting Point: 15-17°C
Boiling Point: 239-240°C
Flash Point: 113°C (closed cup)
Evaporation Rate: Not readily available, likely slow
Solubility: Miscible with common organic solvents (ethanol, acetone, ether), slightly soluble in water
Vapor Pressure: Low at 20°C
Density: 1.08 g/cm³ at 20°C
Partition Coefficient (log Kow): Estimated 0.1–0.5
Viscosity: Not specified
Upper/Lower Flammability: Data not specified, treat as combustible liquid

Stability and Reactivity

Chemical Stability: Stable in normal handling, may slowly absorb moisture
Incompatible Materials: Strong oxidizers, strong acids, certain metals; avoid strong bases that can increase reactivity
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, possible formation of other unspecified hazardous gases
Reactivity: Non-reactive under standard conditions, highly exothermic with strong oxidants

Toxicological Information

Routes of Exposure: Inhalation, skin absorption, ingestion, eye contact
Acute Effects: Eye and skin irritation, possible headache or dizziness after inhalation
Chronic Effects: No data on reproductive toxicity or carcinogenicity, repeated contact may cause dermatitis
LD50 (Oral, Rat): Estimated >2000 mg/kg based on structurally similar compounds
Sensitization: Not classified as skin sensitizer
Further Effects: No data suggesting mutagenicity or teratogenicity; standard laboratory care reduces risk

Ecological Information

Ecotoxicity: Limited data, low anticipated acute aquatic toxicity
Persistence and Degradability: Readily biodegradable in environmental conditions
Bioaccumulation Potential: Expected to be low, low log Kow value
Mobility in Soil: Moderate mobility, unlikely to persist
Other Hazards: Large spills could cause localized pollution; prevent chemical from entering bodies of water

Disposal Considerations

Waste Treatment Methods: Incinerate in an approved facility, or dispose through licensed hazardous waste contractor
Contaminated Packaging: Rinse with suitable solvent before recycling or disposal, follow local regulations
Special Disposal Instructions: Manage as hazardous organic waste; do not release into drains or environment

Transport Information

UN Number: Not regulated under UN shipping codes
Proper Shipping Name: Chemical, non-hazardous for transport unless packaged in large quantities
Transport Hazard Class: Not listed as dangerous goods for road, air, or sea regulations
Packing Group: Not applicable
Environmental Hazards: Not classified as environmentally hazardous for transport
Special Precautions: Avoid direct sunlight, high temperatures, and impacts during transport; ensure secure, leak-proof containers

Regulatory Information

Inventory Status: Listed on TSCA (USA), REACH (EU), DSL (Canada), or equivalent national inventories
Labeling: Requires use of warning pictograms and phrases per local workplace hazard regulations
Other Regulations: Not subject to major restrictions; follow all regional, national, and international safety and environmental legislation
Workplace Controls: Employers set safety training, emergency response plans for spills or exposures